Abstract View

Author(s): Md. Ahad Ali1, Md. Abu Bin Hasan Susan2

Email(s): 1susan@du.ac.bd

Address:

    Department of Chemistry1 and Dhaka University Nanotechnology Center (DUNC)1,2, University of Dhaka, Dhaka 1000, Bangladesh

Published In:   Volume - 2,      Issue - 2,     Year - 2022

DOI: 10.55878/SES2022-2-2-5  

 View HTML        View PDF

Please allow Pop-Up for this website to view PDF file.

ABSTRACT:
Binary mixtures of an ionic liquid, 1-ethyl-3-methylimidazolium ethyl sulfate ([C2mim]C2H5SO4) with propane-1-ol were prepared over an entire composition range and density, dynamic viscosity, and refractive index at T = 293.15 to T = 333.15 K at atmospheric pressure were measured. The excess properties for the binary systems were determined and successfully fitted to a polynomial equation of the Redlich–Kister type. The variation of excess thermodynamic parameters predicted stronger intermolecular interactions and effective packing in the binary system compared to components. Thermodynamic activation parameters were also calculated from the Eyring equation, which varied with the concentration of [C2mim]C2H5SO4. The variation of these parameters also suggested the presence of strong heteromolecular interactions. The near-infrared (NIR) spectroscopic measurements were conducted in the temperature range from 293.15 K to 333.15 K and spectral variations were analyzed. The NIR data were further evaluated using principal component analysis (PCA) and two-dimensional (2D) correlation spectroscopy. The predicted molecular-level interactions mainly come from different types of HBs formed between unlike molecules in the binary system. The binary mixture may open up a plethora of possible uses due to its novel, distinctive molecular-level interactions, and favorable thermodynamic properties.

Cite this article:
Md. Ahad Ali, Md. Abu Bin Hasan Susan (2023). Volumetric and Spectroscopic Studies of 1-ethyl-3-methylimidazolium Ethylsulfate/Propane-1-ol Binary Mixtures at Different Temperatures. Spectrum of Emerging Sciences, 2(2), pp. 17-28. 10.55878/SES2022-2-2-5DOI: https://doi.org/10.55878/SES2022-2-2-5



[1] Freemantle M. An Introduction to Ionic Liquids. RSC Publishing; 2010.

[2] Angell CA, Ansari Y, Zhao Z. Ionic liquids: Past, present and uuture. Faraday Discuss 2012;154: 9–27. https://doi.org/10.1039/C1FD00112D.

[3] Tokuda H, Hayamizu K, Ishii K, Susan MABH, Watanabe M. Physicochemical properties and structures of room temperature ionic liquids. 1. Variation of anionic species. J. Phys. Chem. B 2004;108(42):16593–16600. https://doi.org/10.1021/jp047480r.

[4] Tokuda H, Hayamizu K, Ishii K, Susan MABH, Watanabe M. Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 2. Variation of alkyl chain length in imidazolium cation. J. Phys. Chem. B 2005;109(13):6103–6110. https://doi.org/10.1021/jp044626d.

[5] Tokuda H, Ishii K, Susan MABH, Tsuzuki S, Hayamizu K, Watanabe M. Physicochemical properties and structures of room temperature ionic liquids. 3. Variation of cationic structures. J. Phys. Chem. B 2005;110 (6):2833-2839. https://doi.org/10.1021/jp053396f.

[6] Plechkova VN, Seddon KR. Applications of ionic liquids in the chemical industry. Chem. Soc. Rev. 2008; 37:123-150. https://doi.org/10.1039/B006677J.

[7] Islam MM, Ahmed S, Miran MS, Susan MABH. Advances on potential-driven growth of metal crystals from ionic liquids. Prog. Cryst. Growth Charact. Mater. 2022;68(4):100580. https://doi.org/10.1016/j.pcrysgrow.2022.100580;

[8] Parvulescu VI, Hardacre C. Catalysis in ionic liquids. Chem. Rev. 2007; 107:2615-2665. https://doi.org/10.1021/cr050948h.

[9] Ara G, Miran MS, Islam MM, Mollah MY, Rahman MM, Susan MABH. 1, 8-Diazabicyclo [5.4. 0]-undec-7-ene based protic ionic liquids and their binary systems with molecular solvents catalyzed Michael addition reaction. New J. Chem. 2020;44(32):13701-6. http://dx.doi.org/10.1039/D0NJ03012K.

[10] Deguchi Y, Nakamura N, Ohno H, Thermoresponsive ionic liquid/water mixtures for separation and purification technologies. Sep. Purif. Technol. 2020; 251:117286. https://doi.org/10.1016/j.seppur.2020.117286.

[11] Doyle M, Choi SK, Proulx G. High‐Temperature Proton conducting mMembranes based on perfluorinated ionomer membrane‐ionic liquid composites. J. Electrochem. Soc. 2020; 147:34. https://doi.org/10.1149/1.1393153.

[12] Sakaebe H, Matsumoto H. N-methyl-propylpiperidinium bis(trifluoromethanesulfonyl)- imide (PP13-TFSI) - Novel electrolyte base for Li battery, Electrochem. Commun.2003;5:594-618. https://doi.org/10.1016/S1388-2481(03)00137-1.

[13] Sato T, Masuda G, Takagi K. Electrochemical properties of novel ionic liquids for electric double layer capacitor applications. Electrochim. Acta2004;49:3603-11. https://doi.org/10.1016/j.electacta.2004.03.030.

[14] Papageorgiou N, Athanassov Y, Armand M, Bonhote P, Pettersson H,
Azam A, Gratzel M. The performance and stability of ambient temperature molten salts for solar cell applications. J. Electrochem. Soc. 1996; 143:3099-3108. DOI: 10.1149/1.1837171.

[15] Noda A, Susan MABH, Kudo K, Mitsushima S, Hayamizu K,
Watanabe M. Brønsted acid−base ionic liquids as proton-conducting nonaqueous electrolytes. J. Phys. Chem. B 2003; 107:4024-4033. https://doi.org/10.1021/jp022347p.

[16] Susan MABH, Noda A, Mitsushima S, Watanabe M. Brønsted acid–base ionic liquids and their use as new materials for anhydrous proton conductors. Chem.
Commun. 2003; 327:938-939. https://doi.org/10.1039/B300959A.

[17] Yang X, Song H, Wang J, Zou W. Temperature and composition dependence of the density, viscosity and refractive index of binary mixtures of a novel gemini ionic liquid with acetonitrile. RSC Adv. 2016; 6:29172–29181. https://doi.org/10.1039/C5RA27934H.

[18] Seddon KR, Stark A, Torres MJ. Influence of chloride, water and organic solvents on the physical properties of ionic liquids. Pure. Appl. Chem. 2000; 72:2275-2287. https://doi.org/10.1351/pac200072122275.

[19] Calvar N, Gonzalez B, Dominguez A, Tojo J. Physical properties of the ternary mixture ethanol + water + 1-butyl-3-methylimidazolium chloride at 298.15 K J. Solution Chem. 2006;35:1217–1225. https://doi.org/10.1007/s10953-006-9073-6.

[20] Zafarani-Moattar, MT, Shekaari H. Volumetric and speed of sound of ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate with acetonitrile and methanol at T = (298.15 to 318.15) K. J. Chem. Eng. Data. 2005; 50:1694-1699. https://doi.org/10.1021/je050165t.

[21] González EJ, Alonso L, Domínguez Á. Physical properties of binary mixtures of the ionic liquid 1-methyl-3-octylimidazolium chloride with methanol, ethanol, and 1-propanol at T = (298.15, 313.15, and 328.15) K and at P = 0.1 mpa. J. Chem. Eng. Data 2006;51(4): 1446–1452. https://doi.org/10.1021/je060123k.

[22] Alkhaldi KH, Al-Jimaz AS, AlTuwaim MS. Liquid extraction of toluene from heptane, octane, or nonane using mixed ionic solvents of 1-ethyl-3-methylimidazolium methylsulfate and 1-hexyl-3-methylimidazolium hexafluorophosphate. J. Chem. Eng. Data. 2018;64(1):169-75. https://doi.org/10.1021/acs.jced.8b00669.

[23] Garcia-Miaja G, Troncoso J, Romani L. Excess enthalpy, density, and heat capacity for binary systems of alkylimidazolium-based ionic liquids+ water. J. Chem. Thermodyn. 2009;41(2):161-6. https://doi.org/10.1016/j.jct.2008.10.002.

[24] González EJ, González B, Calvar N, Domínguez Á. Physical properties of binary mixtures of the ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate with several alcohols at T=(298.15, 313.15, and 328.15) K and atmospheric pressure. J. Chem. Eng. Data. 2007;52(5):1641-8. https://doi.org/10.1021/je700029q.

[25] Lehmann J, Rausch MH, Leipertz A, Fröba AP. Densities and excess molar volumes for binary mixtures of ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate with solvents. J. Chem. Eng. Data. 2010;55(9):4068-74. https://doi.org/10.1021/je1002237.

[26] Welton T. Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chemical reviews. 1999;99(8):2071-84. https://doi.org/10.1021/cr980032t.

[27] Marium M, Rahman MM, Mollah MY, Susan MABH. Molecular level interactions in binary mixtures of 1-ethyl 3-methylimidazolium tetrafluoroborate and water. RSC Adv. 2015;5(26):19907-13. https://doi.org/10.1039/C5RA00083A.

[28] Kiefer J, Molina MM, Noack K. The peculiar nature of molecular interactions between an imidazolium ionic liquid and acetone. Chem. Phys. Chem. 2012;13:1213 – 1220. https://doi.org/10.1002/cphc.201100845.

[29] Chang HC, Jiang JC, Liou YC, Hung CH, Lai TY, Lin SH. Effects of water and methanol on the molecular organization of 1-butyl-3-methylimidazolium tetrafluoroborate as functions of pressure and concentration. J. Chem. Phys. 2008;129(4):044506. https://doi.org/10.1063/1.2958256.

[30] Wang J, Tian Y, Zhao Y, Zhuo K. A volumetric and viscosity study for the mixtures of 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid with acetonitrile, dichloromethane, 2-butanone and N, N-dimethylformamide. Green Chem. 2003;5:618-622. https://doi.org/10.1039/B303735E.

[31] Vogel H. Das temperaturabhangigkeitsgesetz der viskositat von flussigkeiten [The temperature-dependent viscosity law for liquids]. Phys. Z. 1921;22:645-6.

[32] Fulcher GS. Analysis of recent measurements of the viscosity of glasses. J. Am. Ceramic Soc. 1925;8(6):339-55. https://doi.org/10.1111/j.1151-2916.1925.tb16731.x.

[33] Tammann GH, Hesse W. Die Abhängigkeit der Viscosität von der Temperatur bie unterkühlten Flüssigkeiten. Zeitschrift für anorganische und allgemeine Chemie. 1926;156(1):245-57. https://doi.org/10.1002%2Fzaac.19261560121.

[34] Ali A, Nain AK. Ultrasonic and volumetric study of binary mixtures of benzyl alcohol with amides. bull. Chem. Soc. Jpn.2002;75(4):681-687. https://doi.org/10.1246/bcsj.75.681.

[35] Yang C, Xu W, Ma P. Thermodynamic Properties of Binary Mixtures of p-Xylene with Cyclohexane, Heptane, Octane, and N-Methyl-2-pyrrolidone at Several Temperatures. J. Chem. Eng. Data 2004; 49:1794-1801. https://doi.org/10.1021/je049776w.

[36] Oswal S, Rathnam MV. Viscosity data of binary mixtures: ethyl acetate + cyclohexane, + benzene, + toluene, + ethylbenzene + carbon tetrachloride, and + chloroform at 303.15 K. Can. J. Chem. 1984;62:2851. DOI: 10.1139/v84-482.

[37] Tokuda H, Tsuzuki S, Susan MABH, Hayamizu K, Watanabe M. How ionic are room-temperature ionic liquids? an indicator of the physicochemical properties. J. Phys. Chem. B 2006;110(39):19593–19600. https://doi.org/10.1021/jp064159v.

[38] Redlich O, Kister AT. Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 1948;40(3):345-348.

[39] Li L, Zhang J, Li Q, Guo B, Zhao T. Sha F. Density, viscosity, surface tension, and spectroscopic properties for binary system of 1,2-ethanediamine + diethylene glycol. Thermochim. Acta 2014; 590:91–99. https://doi.org/10.1016/j.tca.2014.05.034.

[40] Liu, H.;Xu, J. P.;Qu, L. B.;Xiang, B. R. Generalized Two-dimensional correlation near-infrared spectroscopy and principal component analysis of the structures of methanol and ethanol. Sci. China Chem. 2010, 53(5), 1155–1160. https://doi.org/10.1007/s11426-010-0172-2.

[41] Beć KB, Wójcik MJ, Nakajima T. Quantum chemical calculations of basic molecules: Alcohols and Acids. NIR News 2016;27(8):15–21. https://doi.org/10.1255/nirn.1650.

[42] Workman Jr. J, Weyer L. Practical Guide and Spectral Atlas for Interpretive Near-Infrared Spectroscopy. CRC Press; 2008.

[43] Noda I, Ozaki Y. Two-dimensional Correlation Spectroscopy – Applications in Vibrational and Optical Spectroscopy. John Wiley & Sons Ltd; 2004.

 

Related Images:



Recent Images



Synthesis of potassium salts from derivatives of natural acids
PDE based Analysis for Propagation of Disturbance by Users Mobility in Mobile Network System
Probabilistic Model for rGO-enriched nano-ceramics for electro-mechanical study
Heavy Metal Tolerance and Toxicity Studies on- Indigenous Microflora and its Application for Bioremediation
Volumetric and Spectroscopic Studies of 1-ethyl-3-methylimidazolium Ethylsulfate/Propane-1-ol Binary Mixtures at Different Temperatures
The Influence of Soap and Alcohol-based Cleanser on Human Skin
Carbon Quantum Dot and Application: A Review
Stabilization and Solidification: A solution to the excessive pollution released by The INEOS Neville Plant
Study of etnano-medicinal plant of Himachal Pradesh
Green Synthesis of Zinc Oxide Nanomaterial

Tags


Recomonded Articles: