Abstract View

Author(s): Ratnakar Dutt Shukla1, Byanju Rai2

Email(s): 1rdbhuchem09@gmail.com, 2byanju.rai@gmail.com

Address:

    Department of Chemistry, Pt. DDU Govt. Model College, Bahua, Fatehpur, India

Published In:   Volume - 1,      Issue - 1,     Year - 2021

DOI: Not Available

 View HTML        View PDF

Please allow Pop-Up for this website to view PDF file.

ABSTRACT:
Twenty-first century witnessed the importance of C-H bond functionalization which is regarded as a potent, promising and direct tool for the construction of the carbon-carbon bond. The concept of C-H bond functionalization has been highly explored in the field of synthetic organic chemistry. The current scenario of research is shifted towards the development of novel sustainable protocols which should have great environmental impact. It does not need pre‐functionalization of the substrates and thus offers an atom‐economic strategy hence regarded as green and sustainable approach. The applications of C-H functionalization approach, as a potential synthetic tool, have been well exemplified in the formation of C-C bond and carbon-heteroatom bonds (C-O, C-N, C-S and C-X) which have notable applications in the preparation of complex natural products and medicinally potent compounds. The present review covers the employment of numerous novel and innovative sustainable approaches in the field of C(sp3)-H Functionalization reactions.

Cite this article:
Ratnakar Dutt Shukla, Byanju Rai (2021). Employment of Green and Sustainable Protocols for C(sp3)-H bond Functionalization of 2-Methyl azaarenes and subsequent C-C bond formation. Spectrum of Emerging Sciences, 1(1), pp.21-28.


 

[1]    R. H. Crabtree and A. Lei, Chem. Rev., 2017, 117, 8481-8482.

[2]    H. M. L. Davies and D. Morton, ACS Cent. Sci., 2017, 3, 936-943.

[3]    R. Niu, J. Xiao, T. Liang and X. Li, Org. Lett., 2012, 14, 3, 676-679.

[4]    D. J. Abrams, P. A. Provencher and E. J. Sorensen, Chem. Soc. Rev., 2018, 47, 8925-8967.

[5]    S. K. Sinha, G. Zanoni, and D. Maiti, Asian J. Org.Chem., 2018, 7, 1178-1192.

[6]    P. B. Brady and V. Bhat, Eur. J. Org. Chem., 2017, 5179-5190.

[7]    C. Liu, R. Chen, Y. Shen, Z. Liang, Y. Hua and Y. Zhang, Angew. Chem. Int. Ed., 2017, 56, 8187-8190.

[8]    M. C. Nevase, R. D. Pawar, P. S. Munjal, A. E. Dongare and R.S. Satkar, European Journ. of Pharmaceutical and Medical Research, 2018, 5, 184-192.

[9]    Y. Hamada, DOI: 10.5772/intechopen.74719.

[10] J. P. Michael, Nat. Prod. Rep., 1997, 14, 605.

[11] J. Wiesner, R. Ortmann, H. Jomaa and M. Schlitzer, Angew. Chem. Int. Ed., 2003, 43, 5274.

[12] A. Fournet, R. Hocquemiller, F. Roblot, A. Cave, P. Richomme and J. Bruneton, J. Nat. Prod., 1993, 56, 1547

[13] Y.B.R.D. Rajesh, DOI: 10.5772/intechopen.81239.

[14] A. Kumar, K. Srivastava, R. Kumar, S. K. Puri and P. M. S. Chauhan, Bioorg. Med. Chem. Lett., 2010, 20, 7059.

[15] B. Qian, S. Guo, J. Shao, Q. Zhu, L. Yang, C. Xia and H. Huang, J. Am. Chem. Soc., 2010, 132, 3650-3651.

[16] T.-Y. Feng, H.-X. Li, D. J. Young and J.-P. Lang, J. Org. Chem., 2017, 82, 4113-4120.

[17] A. Muthukumar and G. Sekar, Org. Biomol. Chem., 2017, 15, 691-700.

[18] S. A. R. Mulla, M. Y. Pathan and S. S. Chavan, RSC Adv., 2013, 3, 20281-20286.

[19] H. Komai, T. Yoshino, S. Matsunaga and M. Kanai, Org. Lett., 2011, 13, 1706-1709

[20] J. Wolfling, E. Frank, G. Schnieder, L. F. Tietze, Eur. J. Org. Chem. 2004, 90.

[21] Y. Nakao, K. S. Kanyiva; T. Hiyama, J. Am. Chem. Soc. 2008, 130, 2448.

[22] M. Rueping, N. Tolstoluzhsky, Org. Lett. 2011, 13, 1095

[23] K. Kumari, B. K. Allam and K. N.Singh, RSC Adv., 2014, 4, 19789-19793

[24] D. K. J. Yeung, T. Gao, J. Huang, S. Sun, H. Guo and J. Wang, Green Chem., 2013, 15, 2384-2388.

[25]  A. Kumar and R. D. Shukla, Green Chem., 2015, 17, 848-851

[26] R. Breslow and S. D. Dong, Chem. Rev., 1998, 98, 1997-2011.

[27] H. Dodziuk, Cyclodextrins and Their Complexes, Wiley-VCH, Weinheim, Germany, 2006.

[28] A. Modak, J. Mondal, M. Sasidharan and A. Bhaumik, Green Chem., 2011, 13, 1317-1331.

[29] M. B. Gawande and P. S. Branco, Green Chem., 2011, 13, 3355-3359.

[30]  K. Sato, M. Aoki and R. Noyori, Science, 1998, 281, 1646-1647.

Related Images:



Recent Images



The Influence of Soap and Alcohol-based Cleanser on Human Skin
Surgery to preserve the spleen with cardiac involvement in hydatid cyst diseases
Sulphur and phosphorus containing compounds as green corrosion inhibitors
Thermal analysis of Exhaust manifold system using computational fluid dynamics
Image Fusion using Wavelet Transform: Systematic Literature Review
Fractional PDE based Image Restoration using Grunwald Approximation
Employment of Green and Sustainable Protocols for C(sp3)-H bond Functionalization of 2-Methyl azaarenes and subsequent C-C bond formation
Role of IoT, web services, and chemical science against coronavirus
Green Synthesis and Characterization of Zirconia Nanoparticles using Extract of Citrus sinensis Peels and its Comparative Antibacterial Activity with Cefotaxime

Tags


Recomonded Articles: