Abstract View

Author(s): Ratnakar Dutt Shukla1, Byanju Rai2

Email(s): 1rdbhuchem09@gmail.com, 2byanju.rai@gmail.com

Address:

    Department of Chemistry, Pt. DDU Govt. Model College, Bahua, Fatehpur, India

Published In:   Volume - 1,      Issue - 1,     Year - 2021

DOI: Not Available

 View HTML        View PDF

Please allow Pop-Up for this website to view PDF file.

ABSTRACT:
Twenty-first century witnessed the importance of C-H bond functionalization which is regarded as a potent, promising and direct tool for the construction of the carbon-carbon bond. The concept of C-H bond functionalization has been highly explored in the field of synthetic organic chemistry. The current scenario of research is shifted towards the development of novel sustainable protocols which should have great environmental impact. It does not need pre‐functionalization of the substrates and thus offers an atom‐economic strategy hence regarded as green and sustainable approach. The applications of C-H functionalization approach, as a potential synthetic tool, have been well exemplified in the formation of C-C bond and carbon-heteroatom bonds (C-O, C-N, C-S and C-X) which have notable applications in the preparation of complex natural products and medicinally potent compounds. The present review covers the employment of numerous novel and innovative sustainable approaches in the field of C(sp3)-H Functionalization reactions.

Cite this article:
Ratnakar Dutt Shukla, Byanju Rai (2021). Employment of Green and Sustainable Protocols for C(sp3)-H bond Functionalization of 2-Methyl azaarenes and subsequent C-C bond formation. Spectrum of Emerging Sciences, 1(1), pp.21-28.


 

[1]    R. H. Crabtree and A. Lei, Chem. Rev., 2017, 117, 8481-8482.

[2]    H. M. L. Davies and D. Morton, ACS Cent. Sci., 2017, 3, 936-943.

[3]    R. Niu, J. Xiao, T. Liang and X. Li, Org. Lett., 2012, 14, 3, 676-679.

[4]    D. J. Abrams, P. A. Provencher and E. J. Sorensen, Chem. Soc. Rev., 2018, 47, 8925-8967.

[5]    S. K. Sinha, G. Zanoni, and D. Maiti, Asian J. Org.Chem., 2018, 7, 1178-1192.

[6]    P. B. Brady and V. Bhat, Eur. J. Org. Chem., 2017, 5179-5190.

[7]    C. Liu, R. Chen, Y. Shen, Z. Liang, Y. Hua and Y. Zhang, Angew. Chem. Int. Ed., 2017, 56, 8187-8190.

[8]    M. C. Nevase, R. D. Pawar, P. S. Munjal, A. E. Dongare and R.S. Satkar, European Journ. of Pharmaceutical and Medical Research, 2018, 5, 184-192.

[9]    Y. Hamada, DOI: 10.5772/intechopen.74719.

[10] J. P. Michael, Nat. Prod. Rep., 1997, 14, 605.

[11] J. Wiesner, R. Ortmann, H. Jomaa and M. Schlitzer, Angew. Chem. Int. Ed., 2003, 43, 5274.

[12] A. Fournet, R. Hocquemiller, F. Roblot, A. Cave, P. Richomme and J. Bruneton, J. Nat. Prod., 1993, 56, 1547

[13] Y.B.R.D. Rajesh, DOI: 10.5772/intechopen.81239.

[14] A. Kumar, K. Srivastava, R. Kumar, S. K. Puri and P. M. S. Chauhan, Bioorg. Med. Chem. Lett., 2010, 20, 7059.

[15] B. Qian, S. Guo, J. Shao, Q. Zhu, L. Yang, C. Xia and H. Huang, J. Am. Chem. Soc., 2010, 132, 3650-3651.

[16] T.-Y. Feng, H.-X. Li, D. J. Young and J.-P. Lang, J. Org. Chem., 2017, 82, 4113-4120.

[17] A. Muthukumar and G. Sekar, Org. Biomol. Chem., 2017, 15, 691-700.

[18] S. A. R. Mulla, M. Y. Pathan and S. S. Chavan, RSC Adv., 2013, 3, 20281-20286.

[19] H. Komai, T. Yoshino, S. Matsunaga and M. Kanai, Org. Lett., 2011, 13, 1706-1709

[20] J. Wolfling, E. Frank, G. Schnieder, L. F. Tietze, Eur. J. Org. Chem. 2004, 90.

[21] Y. Nakao, K. S. Kanyiva; T. Hiyama, J. Am. Chem. Soc. 2008, 130, 2448.

[22] M. Rueping, N. Tolstoluzhsky, Org. Lett. 2011, 13, 1095

[23] K. Kumari, B. K. Allam and K. N.Singh, RSC Adv., 2014, 4, 19789-19793

[24] D. K. J. Yeung, T. Gao, J. Huang, S. Sun, H. Guo and J. Wang, Green Chem., 2013, 15, 2384-2388.

[25]  A. Kumar and R. D. Shukla, Green Chem., 2015, 17, 848-851

[26] R. Breslow and S. D. Dong, Chem. Rev., 1998, 98, 1997-2011.

[27] H. Dodziuk, Cyclodextrins and Their Complexes, Wiley-VCH, Weinheim, Germany, 2006.

[28] A. Modak, J. Mondal, M. Sasidharan and A. Bhaumik, Green Chem., 2011, 13, 1317-1331.

[29] M. B. Gawande and P. S. Branco, Green Chem., 2011, 13, 3355-3359.

[30]  K. Sato, M. Aoki and R. Noyori, Science, 1998, 281, 1646-1647.

Related Images:



Recent Images



Synthesis of potassium salts from derivatives of natural acids
PDE based Analysis for Propagation of Disturbance by Users Mobility in Mobile Network System
Probabilistic Model for rGO-enriched nano-ceramics for electro-mechanical study
Heavy Metal Tolerance and Toxicity Studies on- Indigenous Microflora and its Application for Bioremediation
Volumetric and Spectroscopic Studies of 1-ethyl-3-methylimidazolium Ethylsulfate/Propane-1-ol Binary Mixtures at Different Temperatures
The Influence of Soap and Alcohol-based Cleanser on Human Skin
Carbon Quantum Dot and Application: A Review
Stabilization and Solidification: A solution to the excessive pollution released by The INEOS Neville Plant
Study of etnano-medicinal plant of Himachal Pradesh
Green Synthesis of Zinc Oxide Nanomaterial

Tags


Recomonded Articles:

Author(s): Bhupendra Kande, Prachi Parmar

DOI: 10.55878/SES2022-2-1-3         Access: Open Access Read More

Author(s): B. D. Patel

DOI:         Access: Open Access Read More

Author(s): Shathya Pranav Sujithra Rajesh Kannan

DOI: 10.55878/SES2022-2-2-1         Access: Open Access Read More